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Evaluation of adsorption parameters and heats of adsorption through desorption measurements

Saha, Bidyut B., Koyama, Shigeru, El-Sharkawy, II, Habib, Khairul, Srinivasan, Kandadai and Dutta, Pradip (2007). Evaluation of adsorption parameters and heats of adsorption through desorption measurements. Journal of Chemical and Engineering Data,52(6):2419-2424.

Document type: Journal Article
Citation counts: Scopus Citation Count Cited 26 times in Scopus Article | Citations

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Title Evaluation of adsorption parameters and heats of adsorption through desorption measurements
Author Saha, Bidyut B.
Koyama, Shigeru
El-Sharkawy, II
Habib, Khairul
Srinivasan, Kandadai
Dutta, Pradip
Journal Name Journal of Chemical and Engineering Data
Publication Date 2007
Volume Number 52
Issue Number 6
ISSN 0021-9568   (check CDU catalogue  open catalogue search in new window)
Scopus ID 2-s2.0-36849060278
Start Page 2419
End Page 2424
Total Pages 6
Place of Publication New York, United States of America
Publisher American Chemical Society
HERDC Category C1 - Journal Article (DEST)
Abstract The construction of an apparatus for the rapid measurement of the adsorption equilibrium characteristics and evaluation of the isosteric heat of adsorption of activated carbons for gaseous adsorbates is described. The method is based on measuring the amount desorbed between two equilibrium adsorption states. The measurement system has been tested for methane adsorption over (5 to 75) degrees C and pressures from (2 to 24) bar on a Maxsorb-III specimen of activated carbon. The results are evaluated through regressions with various isotherm equations used in the literature for physisorption and are compared with results of other researchers for comparable adsorbent-adsorbate combinations. A method of accounting for the adsorbed phase volume is proposed.
Keywords HIGH-PRESSURE ADSORPTION
ADSORBED NATURAL-GAS
ACTIVATED CARBON
SUPERCRITICAL METHANE
STORAGE-SYSTEM
NITROGEN
EQUILIBRIA
ARGON
ISOTHERMS
EQUATION
DOI http://dx.doi.org/10.1021/je700369j   (check subscription with CDU E-Gateway service for CDU Staff and Students  check subscription with CDU E-Gateway in new window)
 
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